10 August 2020
Fraunhofer ISE sets efficiency record of 25.9% for III-V/Si tandem cell grown directly on silicon
In photovoltaics, intensive research is being carried out to continually improve solar cell efficiency. Increasingly, the focus is on tandem photovoltaics, in which high-performance solar cell materials are brought together in various combinations in order to use the solar spectrum even more efficiently when converting light into electrical energy. Fraunhofer Institute for Solar Energy Systems ISE of Freiburg, Germany has now reported a record efficiency of 25.9% for a III-V/silicon tandem solar cell grown directly on silicon. This cell was produced on a low-cost silicon substrate for the first time – marking an important milestone on the way to economical solutions for tandem photovoltaics.
Picture: Several III-V tandem solar cells on a 10cm-diameter silicon substrate.
Fraunhofer ISE has been working for many years on multi-junction solar cells, in which two or three sub-cells stacked on top of another absorb different portions of the solar spectrum and convert it into electricity. Silicon is a suitable absorber for the infrared part of the spectrum. Several micron-thin layers of III-V compound semiconductors are deposited on top of the silicon. These sub-cells efficiently convert light from the ultraviolet, visible and near-infrared parts of the spectrum into electricity.
III-V solar cells on germanium substrates are often used in space as well as in concentrator photovoltaics (CPV). Through the development of better and more cost-effective processes in combination with the use of silicon as the bottom sub-cell, tandem technology can become accessible for wide-range use in almost all photovoltaic applications in the future, says Fraunhofer ISE. However, there is still much work to be done before this objective can be achieved.
25.9% for III-V/Si tandem solar cells grown directly on silicon
Several different approaches for producing combinations of III-V and silicon solar cells exist. For example, Fraunhofer ISE held the record efficiency of 34.1% (now 34.5%) for a tandem solar cell in which the III-V layers are transferred from a gallium arsenide to a silicon substrate and connected by wafer bonding. This technology is very efficient but expensive.
For this reason, Fraunhofer ISE has been working for many years on more direct manufacturing processes in which the III-V layers are grown directly onto a silicon solar cell. In this process it is crucial that all layers maintain high crystal quality, and this presents a major challenge. Now a new efficiency record of 25.9% has been achieved for a III-V/Si tandem solar cell grown directly on silicon.
Graphic: III-V/Si multi-junction solar cell layer structure, quantum efficiency and IV characteristics under AM1.5g spectral conditions.
Fraunhofer ISE’s Markus Feifel recently presented his results at the (online) 47th IEEE Photovoltaic Specialists Conference (15 June – 21 August), where his work was distinguished with the Student Award in the Category of Hybrid Tandem Solar Cells. “The complex inner structure of the cell is not visible from the outside, since all of the separate absorbers are internally interconnected by additional crystal layers and electrically series connected,” says Feifel, who was able to improve his results from 24.3% to 25.9% in less than a year. “This was achieved by replacing a single thin layer within the multi-junction cell,” he adds. “A careful analysis of our cells showed that this layer created a potential barrier for electrons moving through the crystal structure.”
Since 2007 the Fraunhofer researchers have been developing this technology in small steps together with the Ilmenau University of Technology, the Philipps University of Marburg and deposition system manufacturer Aixtron, for example setting up special epitaxial equipment and examining every single layer of the structure. These developments were funded by the German Federal Ministry of Education and Research (BMBF) as part of the III-V-Si project and the MehrSi project.
A particular highlight of the new tandem solar cell is that the III-V layers were not grown on a chemo-mechanically polished substrate, as in previous cases, but directly on a silicon wafer which, after sawing, was treated in a simple process using only inexpensive grinding and etching processes. The Danish company Topil developed this silicon wafer in the European SiTaSol project, realizing an important step towards the economical production of the new multi-junction solar cells.
In the future, the focus will be to increase the efficiency even further as well as to realize faster layer deposition, with higher throughput, and thus improve the cost-effectiveness of production. The ultimate objective is that tandem photovoltaics will be able to make an important contribution to the expansion of photovoltaics.
Key technology for energy transition
In many parts of the world, electricity from solar cells is the cheapest form of energy generation. “In Europe the photovoltaic research community is working on numerous concepts to further improve the efficiency of this key technology, which plays a central role in the energy transition,” says professor Stefan Glunz, Division Director of the Photovoltaics Research at Fraunhofer ISE. “Not only are we working to make silicon solar cell production more sustainable and cost effective but we are also breaking new ground,” he adds. “We are aiming to reach even higher efficiencies using the tried and tested silicon in combination with other semiconductor materials, and have achieved this in the field of tandem photovoltaics.”
This technology not only opens the door to the future of power generation but is also suited to electrolysis (i.e. using electricity to split water into hydrogen and oxygen). Thus, tandem photovoltaics can be used to produce hydrogen, an energy storage medium and important building block for the energy transition.